2-Methylanilinium dihydrogen phosphate–phosphoric acid (1/1)
نویسندگان
چکیده
In the title compound, C(7)H(10)N(+)·H(2)PO(4) (-)·H(3)PO(4), there is a clear distinction between the P-O/P=O and P-OH bond lengths. In the crystal, the H(2)PO(4) (-) anions and H(3)PO(4) mol-ecules are linked by O-H⋯O hydrogen bonds, leading to layers propagating in the bc plane. The organic cations are located between these layers and inter-act with them by way of N-H⋯O hydrogen bonds.
منابع مشابه
1-(2-Bromoethyl)-1,4-diazoniabicyclo[2.2.2]octane bromide dihydrogen phosphate–phosphoric acid (1/1)
In the crystal structure of the title compound, C(8)H(17)BrN(2) (2+)·Br(-)·H(2)PO(4) (-)·H(3)PO(4), the cations, anions and phospho-ric acid mol-ecules are linked by O-H⋯O, N-H⋯O and O-H⋯Br hydrogen bonds into layers parallel to (101).
متن کامل2-Phenylimidazole dihydrogen phosphate phosphoric acid
The crystal structure of the title compound, C(9)H(9)N(2) (+)·H(2)PO(4) (-)·H(3)PO(4), is stabilized by N-H⋯O and O-H⋯O hydrogen-bonding inter-actions, resulting in a two-dimensional network.
متن کامل2,6-Diethylanilinium dihydrogen phosphate–phosphoric acid (1/1)
In the crystal structure of the title salt, C(10)H(16)N(+)·H(2)PO(4) (-)·H(3)PO(4), the H(2)PO(4) (-) and H(3)PO(4) components are connected into infinite chains extending along the b-axis direction by way of O-H⋯O links. These chains are also linked through O-H⋯O hydrogen bonds thus building up a supra-molecular two-dimensional framework extending parallel to (001). The organic cations cross-l...
متن کامل4-Cyanopyridinium dihydrogen phosphate–isonicotinonitrile–phosphoric acid (1/1/1)
The asymmetric unit of the title compound, C(6)H(5)N(2) (+)·H(2)PO(4) (-)·C(6)H(4)N(2)·H(3)PO(4), contains one 4-cyano-pyridinium cation, one H(2)PO(4) (-) anion, one independent isonicotinonitrile mol-ecule and one independent H(3)PO(4) mol-ecule. The dihedral angle between the mean planes of the separate protonated and unprotonated pyridine rings is 9.93 (8)°. In the crystal, N-H⋯O and O-H⋯N ...
متن کاملReinvestigation of 4-methylanilinium dihydrogen phosphite
The crystal structure of the title compound, C(7)H(10)N(+)·H(2)PO(3) (-), has been reported previously by Sabounchei & Naghipour [Asian J. Chem. (2003) ▶, 15, 1677-1686]. A new look at this compound has revealed doubling of the unit cell. The asymmetric unit consists of two 4-methyl-anilinium cations and two dihydrogen phosphite anions. The crystal structure is built upon alternating layers of ...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009